Base Name NomenclatureThe Phenyl and Benzyl GroupsCommonly Named Benzene Compounds Nomenclature Summary FlowchartPractice Problems
Unlike aliphatic organics, nomenclature of benzene-derived compounds can be confusing because a single aromatic compound can have multiple possible names (such as common & systematic names) be associated with its structure. In these sections, we will analyze some of the ways these compounds can be named.
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Simple Benzene Naming
Some common substituents, like NO2, Br, & Cl, can be named this way when it is attached khổng lồ a phenyl group. Long chain carbons attached can also be named this way. The general format for this kind of naming is:
(positions of substituents (if >1)- + # (di, tri, ...) + substituent)n + benzene.
For example, chlorine (Cl) attached lớn a phenyl group would be named chlorobenzene (chloro + benzene). Since there is only one substituent on the benzene ring, we do not have to indicate its position on the benzene ring (as it can freely rotate around & you would over up getting the same compound.)
Ortho-, Meta-, Para- (OMP) Nomenclature for Disubstituted Benzenes
Instead of using numbers khổng lồ indicate substituents on a benzene ring, ortho- (o-), meta- (m-), or para (p-) can be used in place of positional markers when there are two substituents on the benzene ring (disubstituted benzenes). They are defined as the following:ortho- (o-): 1,2- (next khổng lồ each other in a benzene ring) meta- (m): 1,3- (separated by one carbon in a benzene ring) para- (p): 1,4- (across from each other in a benzene ring)
Using the same example above in figure 9a (1,3-dichlorobenzene), we can use the ortho-, meta-, para- nomenclature to lớn transform the glaskragujevca.netical name into m-dichlorobenzene, as shown in the figure below.
Here are some other examples of ortho-, meta-, para- nomenclature used in context:
However, the substituents used in ortho-, meta-, para- nomenclature bởi not have lớn be the same. For example, we can use chlorine and a nitro group as substituents in the benzene ring.
In conclusion, these can be pieced together into a summary diagram, as shown below:
Alternatively, we can use the numbering system to lớn indicate this compound. When the numbering system is used, the carbon where the substituent is attached on the base will be given the first priority and named as carbon #1 (C1). The normal priority rules then apply in the nomenclature process (give the rest of the substituents the lowest numbering as you could).
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Additionally, other substituents can attach on the benzene ring in the presence of the benzyl group. An example of this can be seen in the figure below:
api/deki/files/2302/BenzeneFlow.png?revision=1&size=bestfit&width=720&height=911" />Summary Flowchart (Figure 24). Summary of nomenclature rules used in commonly benzene derived compounds.As benzene derived compounds can be extremely complex, only compounds covered in this article & other commonly named compounds can be named using this flowchart.
Determination of Common và Systematic Names using Flowchart
To demonstrate how this flowchart can be used khổng lồ name TNT in its common và systematic (IUPAC) name, a replica of the flowchart with the appropriate flow paths are shown below: